Understanding the exposure of the nation’s living marine resources such as shellfish and corals to changing ocean chemistry is a primary goal for the NOAA OAP. Repeat hydrographic surveys, ship-based surface observations, and time series stations (mooring and ship-based) in the Atlantic, Pacific, and Indian Oceans have allowed us to begin to understand the long-term changes in carbonate chemistry in response to ocean acidification.
When the ocean absorbs carbon dioxide, chemical reactions create hydrogen ions that act like free agents, able to react with other compounds. Two ways we track ocean acidification are through pH and total alkalinity (TA). pH is a measure of how many free hydrogen ions are in the seawater. The more carbon dioxide in the ocean, the more these free agents are created, causing lower pH (more acidic).
The partial pressure of CO2 (pCO2) tells us how much carbon dioxide is in seawater. This information helps us understand ocean carbonate chemistry and biological productivity in the region. pCO2 increases when the ocean absorbs more CO2 from the atmosphere with elevated emissions.
Alkalinity is the ocean’s buffering system against increasing acidity. Total alkalinity is a measure of the concentration of buffering molecules like carbonate and bicarbonate in the seawater that can neutralize acid.
Dissolved inorganic carbon (DIC) tells us how much non-biological carbon is in seawater. Inorganic carbon comes in three main forms that we measure for DIC: carbon dioxide (CO2), bicarbonate (HCO3-), and carbonate (CO32-). Understanding DIC can help us determine the balance of carbonate forms in the ocean and the likelihood of ocean acidification.
There are currently 19 OAP-supported buoys in coastal, open-ocean and coral reef waters which contribute to NOAA's Ocean Acidification Monitoring Program, with other deployments planned.
Currently, there are two types of floating devices which instruments can be added in order to measure various ocean characteristics - buoys and wave gliders. Buoys are moored, allowing them to remain stationary and for scientists to get measurements from the same place over time. The time series created from these measurements are key to understanding how ocean chemistry is changing over time. There are also buoys moored in the open-ocean and near coral reef ecosystems to monitor the changes in the carbonate chemistry in these ecosystems. The MAP CO2 sensors on these buoys measure pCO2 every three hours.
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Research cruises are a way to collect information about a certain ecosystem or area of interest.
For decades, scientists have learned about physical, chemical and biological properties of the ocean and coasts by observations made at sea. Measurements taken during research cruises can be used to validate data taken by autonomous instruments. One instrument often used on research cruises is a conductivity, temperature, and depth sensor (CTD), which measures the physical state of the water (temperature, salinity, and depth). The sensor often goes in the water on a rosette, which also carries niskin bottles used to collect water samples from various depths in the water column. Numerous chemical and biological properties can be measured from water collected in niskin bottles.
Ships of Opportunity (SOPs) or Volunteer Observing Ships (VOSs) are vessels at sea for other reasons than ocean acidification studies, such as commercial cargo ships or ferries.
The owners of these vessels allow scientific instrumentation that measures ocean acidification (OA) parameters to be installed and collect data while the ship is underway. This allows data on ocean chemistry to be collected in many remote areas of the world's ocean, such as high latitude waters, long distances from land (e.g. mid-basin waters), and places not easily accessible by research cruises. These partnerships have greatly increased the spatial coverage of OA monitoring world-wide. To learn more, check out the Ships of Opportunity programs established by the NOAA Pacific Marine Environmental Laboratory (PMEL) and the NOAA Atlantic Oceanographic Marine Laboratory (AOML).
Scientists at the NOAA Pacific Marine Environmental Laboratory (PMEL) are working with engineers at Liquid Robotics, Inc. to optimize a Carbon Wave Glider.
This instrument (pictured above) can be driven via satellite from land. Carbon Wave Gliders can be outfitted with pCO2, pH, oxygen, temperature and salinity sensors, and the glider’s equipment takes measurements as it moves through the water. The glider’s motion is driven by wave energy, and its sensors are powered through solar cells and batteries, when needed.
NOAA’s Coral Reef Conservation Program (CRCP) in partnership with OAP is engaged in a coordinated and targeted series of field observations, moorings and ecological monitoring efforts in coral reef ecosystems.
These efforts are designed to document the dynamics of ocean acidification (OA) in coral reef systems and track the status and trends in ecosystem response. This effort serves as a subset of a broader CRCP initiative referred to as the National Coral Reef Monitoring Plan, which was established to support conservation of the Nation’s coral reef ecosystems. The OAP contributes to this plan through overseeing and coordinating carbonate chemistry monitoring. This monitoring includes a broadly distributed spatial water sampling campaign complemented by a more limited set of moored instruments deployed at a small subset of representative sites in both the Atlantic/Caribbean and Pacific regions. Coral reef carbonate chemistry monitoring is implemented by researchers at the NOAA Atlantic Oceanographic & Meteorological Laboratory (AOML) and NOAA's PIFSC Coral Reef Ecosystems Division.
NOAA invests $18.9M in a coordinated effort to maximize advances in harmful algal bloom (HAB) mitigation, monitoring and forecasting. Four of new research awards support ($1.5M) funded in partnership by NOAA’s National Centers for Coastal Ocean Science (NCCOS) and NOAA’s Ocean Acidification program will determine interactive effects of HABs and ocean acidification. Other projects supported through this effort will establish a U.S. Harmful Algal Bloom Control Incubator, enhance detection of HAB toxins and improve forecasts and investigate the socioeconomic impacts of HABs. Read more
Project Highlights
University of Michigan, University of Minnesota Duluth, Oberlin College, University of Kentucky, and University of Toledo received $281,975 to improve our understanding of the synergistic impacts of acidification, temperature, total alkalinity, and nutrients on toxic cyanobacteria harmful algal blooms in the Great Lakes.
Woods Hole Oceanographic Institute, Bowdoin College, and NERACOOS received $499,999 to address gaps in understanding relationships between harmful algal bloom behavior and ocean acidification in the northeast Atlantic, especially where it is associated with coastal eutrophication and hypoxia.
Stony Brook University, Adelphi University, and St. Joseph's College received $364,265 to establish a comprehensive understanding of how three of the most prominent HABs on the US east coast respond to ocean acidification, and how their co-occurrence will economically impact fisheries and shellfisheries.
Northwest Indian College, San Francisco State University, and University of Washington received $355,281 to understand the current relationships between ocean acidification and harmful algal bloom interactions in the Salish Sea, and to quantify how ocean acidification influences growth and toxicity.
Autonomous glider collects information to track harmful algal blooms and water quality. Credit: Ben Yair Raanan, MBARI
PMEL Sustained Ocean Acidification Biogeochemical and Ecological Survey Observations
Why we care U.S. West coast-wide hydrographic surveys have been conducted intermittently from 2007 to 2017, providing evidence for the geographic extent and severity of ocean acidification in the continental shelf ecosystem. Scientists on the NOAA West Coast Ocean Acidification (WCOA) discovered that the combined effects of anthropogenic and biologically-derived carbon dioxide resulted in significant biological impacts for oyster larvae and pteropods, which are small, ecologically important mollusks for the food web.
What we are doing This project executes a large-scale survey of ocean acidification carbonate chemistry in the California Current System and continues processing data and publishing scientific papers based on 2016 and 2017 surveys findings. This survey determines the spatial distributions of temperature, salinity, pH, dissolved inorganic carbon, total alkalinity, oxygen, nutrients, and biological parameters along the west coast of North America. Survey results will provide the basis for accurate assessments of changing ocean chemistry in the following areas: 1) spatial variability; 2) extent and causes of long-term changes in carbonate system parameters and their impacts on calcifying (shell-building) organisms; and 3) empirical relationships for obtaining high-resolution information on ocean acidification collected on moorings.
Benefits of our work This project links the combined stressors of increased temperature, acidification, and hypoxia (low oxygen) with effects on marine organisms in the region and identifies spatial variability of acidifying conditions during the spring/summer upwelling season. In addition to scientific partners, this project engages a NOAA Teacher At Sea (TAS) fellow on the cruise to help develop outreach and education on West Coast ocean acidification.
PMEL Sustained Investment Coastal Underway Ocean Acidification Observations (PUO)
Why we care Underway ship measurements of ocean acidification (OA) data on ships of opportunity (SOOP) have proven to be a robust and cost-effective way of expanding OA observations. Ship-based observations provide an understanding of the spatial extent of processes that drive OA. Surface underway observations, in conjunction with coastal moorings and dedicated large-scale surveys, make an important contribution to addressing the hypothesis that acidification varies across space and time as a consequence of local and regional processes.
What we are doing The focus of this project is to sustain existing underway OA monitoring systems on NOAA Ships Oscar Dyson and Bell M. Shimada, which operate along the U.S. West Coast. Project objectives also include sustaining underway OA observations in the equatorial Pacific, upgrading sensor systems, and improving oxygen data collection.
Benefits of our work This project increases high-quality surface water OA data taken underway to accompany NOAA Fisheries cruises. Efforts also improve spatial and temporal coverage of OA measurements, improving our understanding of OA variability along the Pacific coast of North America.
Dr. Nina Bednarsek has been awarded the biennial SeaDoc Society's’ Salish Sea Science Prize for her groundbreaking work on the impacts of ocean acidification on pteropods, planktonic marine snails, as well as enhancing policy and regulatory processes along the US West Coast. Dr. Bednarsek was an NRC postdoctoral research fellow with NOAA Pacific Marine Environmental Laboratory (PMEL) from 2012 - 2015 where she worked with the Carbon Program. Dr. Bednarsek’s research with PMEL has found that the highest impacts on pteropods from ocean acidification is observed in the Salish Sea. Her results show that live pteropod shells undergo dissolution at aragonite saturation state values <1, which is commonly found in subsurface Salish Sea waters and along the Washington coast during the upwelling season.
Ocean acidification (OA) is already harming shellfish species in the Pacific Northwest, a global hotspot of OA. While OA poses a threat to regional communities, economies, and cultures that rely on shellfish, identified gaps remain in adaptive capacity and vulnerability of several stakeholders. This project will address these gaps by extending long-standing collaborative OA vulnerability research with shellfish growers to include other shellfish users (e.g. port towns, Native American tribes and shellfish sector employees). The project includes five objectives: 1) Map variations in shellfisheries’ exposure to OA and identify those that are most sensitive, 2) quantify production losses from OA and costs of investment in adaptation 3) Identify potential pathways for adaptation, 4) identify key technological, institutional, legislative, financial and cultural barriers to OA adaptation, 5) evaluate the cost of potential adaptation strategies, and develop behavioral models to predict the likelihood of users adopting specific adaptation strategies. The research is designed to identify key vulnerabilities, determine the cost of OA to Pacific Northwest shellfish stakeholders, and to model adaptation pathways for maximizing resilience to OA. The adaptation framework developed here will be replicable in other shellfisheries yet to experience OA impacts.