Building on the spectrophotometric procedure of Yao and Byrne (1998), an automated analysis system has been developed for laboratory and shipboard measurements of total alkalinity at a rate of 6 samples per hour. The system is based on single-point hydrochloric acid (HCl) titrations of seawater samples of a known volume with bromocresol purple as an indicator. The titration is continuously monitored using visible spectroscopy to guide the titration rate according to the real-time pH of the samples. Each titration is terminated just below the equivalence point to achieve a precision and accuracy near 1 μmol kg− 1.
An automated procedure for laboratory and shipboard spectrophotometric measurements of seawater alkalinity: Continuously monitored single-step acid additions
- Author(s): Xuewu Liu, Robert H. Byrne, Michael Lindemuth, Regina Easley, Jeremy T. Mathis,
- Marine Chemistry
- August 20, 2015
Citation: Liu, X., Byrne, R. H., Lindemuth, M., Easley, R., & Mathis, J. T. (2015). An automated procedure for laboratory and shipboard spectrophotometric measurements of seawater alkalinity: Continuously monitored single-step acid additions. Marine Chemistry, 174, 141-146. https://doi.org/10.1016/j.marchem.2015.06.008