Conductivity, Temperature, Depth (CTD)
A Conductivity (salinity), Temperature, Depth (CTD) sensor is a key instrument on ocean acidification research cruises. CTD measurements paint a picture of salinity and temperature from surface to seafloor. Temperature and salinity influence water movement, activity by marine life, and water chemistry throughout the ocean. The CTD is linked with a Niskin bottle rosette (pictured). This collector takes water samples at many depths, providing a snapshot of the whole water column. This expands our sampling below surface waters that are continuously monitored by buoys and moorings in our network. Scientists deploy the CTD rosette at every monitoring station during the cruise.
Water Quality
Dissolved Inorganic Carbon (DIC)
The partial pressure of CO2 (pCO2) tells us how much carbon dioxide is in seawater. Sampling on ocean acidification research cruises expands an important time-series of marine carbon dioxide levels. This information helps us understand ocean carbonate chemistry and biological productivity in the region. On ECOA-3, NOAA’s Atlantic Oceanographic and Meteorological Laboratory (AOML) measured pCO2 using an underway system that continuously takes high-quality measurements during the cruise.
Water Chemistry
Partial Pressure of CO2 (pCO2)
Increases in carbon dioxide (known as CO2) in the atmosphere drive corresponding increases in dissolved CO2 within the surface waters of our ocean. This dissolved CO2 reacts with seawater to form carbonic acid (H2CO3). Carbonic acid breaks apart to form bicarbonate ions (HCO3–) and hydrogen ions (H+). Hydrogen ions (H+) act like free agents. And while the ocean is not acidic, these free agent hydrogen ions cause the seawater to become more acidic. We measure this using pH (H represents hydrogen ions). The free agent hydrogen ions also react with carbonate ions (CO32-) to form bicarbonate (HCO3–), making carbonate ions relatively less abundant. Next, find out why this matters next.
Water Chemistry
Total Alkalinity & pH (TA, pH)
When the ocean absorbs carbon dioxide, chemical reactions create hydrogen ions that act like free agents, able to react with other components in the seawater. Two ways we track ocean acidification are through pH and total alkalinity (TA). pH is a measure of how many free hydrogen ions are in the seawater. More carbon dioxide in the ocean creates more of these free agents, causing lower pH (more acidic). Alkalinity is the ocean’s buffering system against increasing acidity. Total alkalinity is a measure of the concentration of buffering molecules like carbonate and bicarbonate in the seawater that can neutralize acid. Researchers aboard ocean acidification research cruises measure pH and TA along the seaboard.
Water Chemistry
Oxygen (O2)
Oxygen is a core measurement taken on coastal and ocean acidification research cruises. Like animals on land, marine life requires sufficient oxygen to live. Ocean oxygen is considered a co-stressor to ocean acidification. Both low oxygen and acidification increase stress on marine life, and they often occur at the same times and places, creating a greater burden for socio-economically important species. On ECOA-3, researchers from the University of Miami researched more about how ocean biogeochemistry controls oxygen saturation. Oxygen is measured onboard using the Winkler titration method.
Water Chemistry
Harmful Algal Blooms & Other Protists
Oxygen is a core measurement taken on coastal and ocean acidification research cruises. Like animals on land, marine life requires sufficient oxygen to live. Ocean oxygen is considered a co-stressor to ocean acidification. Both low oxygen and acidification increase stress on marine life, and they often occur at the same times and places, creating a greater burden for socio-economically important species. On ECOA-3, researchers from the University of Miami researched more about how ocean biogeochemistry controls oxygen saturation. Oxygen is measured onboard using the Winkler titration method.
Ecosystem Health
Sediment
Take a deep dive with the sediment corer from ECOA-3 >
Ecosystem Health
Nutrients
Nitrate, nitrite, ammonium, phosphate and silicate are major inorganic nutrients that control primary production and carbon movement in the ocean. Together with the measurements of inorganic carbon, researchers will estimate the effect of riverine input, air-sea CO2 exchange, biological productivity, and carbon exchange on the coastal carbon dynamics.