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Marine Chemistry

Calcification and organic production on a Hawaiian coral reef

Net ecosystem calcification rates (NEC) and net photosynthesis (NP) were determined from CO2 seawater parameters on the barrier coral reef of Kaneohe Bay, Oahu, Hawaii. Autosamplers were deployed to collect samples on the barrier reef every 2 h for six 48-hour deployments, two each in June 2008, August 2009, and January/February 2010. NEC on the Kaneohe Bay […]

Calcification and organic production on a Hawaiian coral reef Read More »

Seawater pH measurements in the field: A DIY photometer with 0.01 unit pH accuracy

A portable light-emitting-diode (LED) photometer has been developed to provide low-cost seawater pH measurements. The benefits of the new system include a simple “do-it-yourself” construction design, a hundredfold reduction in cost relative to benchtop spectrophotometric systems, routine calibration-free operation in the field, and precision and accuracy well suited to applications such as education, coastal zone

Seawater pH measurements in the field: A DIY photometer with 0.01 unit pH accuracy Read More »

Internal consistency of marine carbonate system measurements and assessments of aragonite saturation state: Insights from two U.S. coastal cruises

This research assesses the thermodynamic consistency of recent marine CO2 system measurements in United States coastal waters. As one means of assessment, we compared aragonite saturation states calculated using various combinations of measured parameters. We also compared directly measured and calculated values of total alkalinity and CO2 fugacity. The primary data set consists of state-of-the-art measurements of the keystone

Internal consistency of marine carbonate system measurements and assessments of aragonite saturation state: Insights from two U.S. coastal cruises Read More »

An inter-laboratory comparison assessing the quality of seawater carbon dioxide measurements

Seawater CO2 measurements are being made with increasing frequency as interest grows in the ocean’s response to changing atmospheric CO2 levels and to climate change. The ultimate usefulness of these measurements depends on the data quality and consistency. An inter-laboratory comparison was undertaken to help evaluate and understand the current reliability of seawater CO2 measurements. Two seawater test samples

An inter-laboratory comparison assessing the quality of seawater carbon dioxide measurements Read More »

Procedures for direct spectrophotometric determination of carbonate ion concentrations: Measurements in US Gulf of Mexico and East Coast waters

Refined procedures were developed for directly determining carbonate ion concentrations in seawater through measurement of the ultraviolet absorbances of lead carbonate and chloride complexes after addition of divalent lead (Pb(II)) to a seawater sample. Our model algorithm is based on carbonate ion concentrations calculated from measurements of pH and dissolved inorganic carbon (DIC) obtained on a NOAA ocean acidification cruise (GOMECC-2, the second Gulf of Mexico and East Coast

Procedures for direct spectrophotometric determination of carbonate ion concentrations: Measurements in US Gulf of Mexico and East Coast waters Read More »

An automated procedure for laboratory and shipboard spectrophotometric measurements of seawater alkalinity: Continuously monitored single-step acid additions

Building on the spectrophotometric procedure of Yao and Byrne (1998), an automated analysis system has been developed for laboratory and shipboard measurements of total alkalinity at a rate of 6 samples per hour. The system is based on single-point hydrochloric acid (HCl) titrations of seawater samples of a known volume with bromocresol purple as an indicator. The titration is continuously monitored using visible spectroscopy to guide the

An automated procedure for laboratory and shipboard spectrophotometric measurements of seawater alkalinity: Continuously monitored single-step acid additions Read More »

Contributions of organic alkalinity to total alkalinity in coastal waters: A spectrophotometric approach

Contributions of organic alkalinity (Org-Alk) to total alkalinity (TA) were investigated in surface waters from three different coastal environments (estuary, urban, mangrove) and offshore sites in the Gulf of Mexico. ∆ TA was calculated as the difference between directly measured TA, and TA calculated from total dissolved inorganic carbon (DIC) and pH. In low nutrient surface waters, ∆ TA should be dominated by Org-Alk with

Contributions of organic alkalinity to total alkalinity in coastal waters: A spectrophotometric approach Read More »

Sea surface aragonite saturation state variations and control mechanisms at the Gray’s Reef time-series site off Georgia, USA (2006–2007)

We report an annual cycle of surface seawater aragonite mineral saturation state (Ωarag) during 2006–2007 at the Gray’s Reef time-series site off Georgia, USA, calculated based on three-hourly observations of carbon dioxide partial pressure (pCO2) and salinity-derived total alkalinity. Ωarag varied between 2.30 and 4.39 with low values (< 3.00) mainly during February–April 2007 and high values (> 3.50) during July–October 2006 and

Sea surface aragonite saturation state variations and control mechanisms at the Gray’s Reef time-series site off Georgia, USA (2006–2007) Read More »

Ocean carbonate system computation for anoxic waters using an updated CO2SYS program

In anoxic/hypoxic waters, the presence of hydrogen sulfide (H2S) and ammonia (NH3) influences results of the computation of parameters in the ocean carbonate system. To evaluate their influences, H2S and NH3 contributions to total alkalinity are added to CO2SYS, which is a most often used publicly available software package that calculates oceanic carbonate parameters. We discuss how these two

Ocean carbonate system computation for anoxic waters using an updated CO2SYS program Read More »

Seasonal variability of carbonate chemistry and decadal changes in waters of a marine sanctuary in the Northwestern Gulf of Mexico

We report seasonal water column carbonate chemistry data collected over a three-year period (late 2013 to 2016) at Flower Garden Banks National Marine Sanctuary (FGBNMS) located on the subtropical shelf edge of the northwestern Gulf of Mexico. The FGBNMS hosts the northernmost tropical coral species in the contiguous United States, with over 50% living coral cover.

Seasonal variability of carbonate chemistry and decadal changes in waters of a marine sanctuary in the Northwestern Gulf of Mexico Read More »

ADAPTING TO OCEAN ACIDIFICATION

The NOAA Ocean Acidification Program (OAP) works to prepare society to adapt to the consequences of ocean acidification and conserve marine ecosystems as acidification occurs. Learn more about the human connections and adaptation strategies from these efforts.

Adaptation approaches fostered by the OAP include:

FORECASTING

Using models and research to understand the sensitivity of organisms and ecosystems to ocean acidification to make predictions about the future, allowing communities and industries to prepare

MANAGEMENT

Using these models and predictions as tools to facilitate management strategies that will protect marine resources and communities from future changes

TECHNOLOGY DEVELOPMENT

Developing innovative tools to help monitor ocean acidification and mitigate changing ocean chemistry locally

REDUCING OUR CARBON FOOTPRINT

On the Road

Drive fuel-efficient vehicles or choose public transportation. Choose your bike or walk! Don't sit idle for more than 30 seconds. Keep your tires properly inflated.

With your Food Choices

Eat local- this helps cut down on production and transport! Reduce your meat and dairy. Compost to avoid food waste ending up in the landfill

With your Food Choices

Make energy-efficient choices for your appliances and lighting. Heat and cool efficiently! Change your air filters and program your thermostat, seal and insulate your home, and support clean energy sources

By Reducing Coastal Acidification

Reduce your use of fertilizers, Improve sewage treatment and run off, and Protect and restore coastal habitats

TAKE ACTION WITH YOUR COMMUNITY

You've taken the first step to learn more about ocean acidification - why not spread this knowledge to your community?

Every community has their unique culture, economy and ecology and what’s at stake from ocean acidification may be different depending on where you live.  As a community member, you can take a larger role in educating the public about ocean acidification. Creating awareness is the first step to taking action.  As communities gain traction, neighboring regions that share marine resources can build larger coalitions to address ocean acidification.  Here are some ideas to get started:

  1. Work with informal educators, such as aquarium outreach programs and local non-profits, to teach the public about ocean acidification. Visit our Education & Outreach page to find the newest tools!
  2. Participate in habitat restoration efforts to restore habitats that help mitigate the effects of coastal acidification
  3. Facilitate conversations with local businesses that might be affected by ocean acidification, building a plan for the future.
  4. Partner with local community efforts to mitigate the driver behind ocean acidification  – excess CO2 – such as community supported agriculture, bike & car shares and other public transportation options.
  5. Contact your regional Coastal Acidification Network (CAN) to learn how OA is affecting your region and more ideas about how you can get involved in your community
       More for Taking Community Action